Material Safety Data Sheet

May be used to Comply with OSHA’s

Hazard Communication Standard,

 29 CFR 1910.1200.  Standard must be

Consulted for specific requirements

HMIS

HEALTH                                                2        REACTIVITY                           0

FLAMMABILITY                               1      PERSONAL PROTECTION   B

Identity (As Used On Label and List)

B4151 Pipe Bond Repair Kit Pressure Off

Note:  Blank spaces are not permitted.  If any item is not applicable, or no information is available, the space must be marked to indicate that.

Section I

Manufactured for:

OMEGA INDUSTRIAL SUPPLY, INC

Emergency Telephone Number:

1-800-424-9300

Address (Number, Street, City, State, and Zip Code)

101 Grobric Ct #1

Telephone Number for Information:

1-800-571-7347

Fairfield, CA 94534

Date Prepared

01-15-2007

 

 

Signature of Prepare (Optional)

REGULATORY DEPT.

Section II - Hazardous Ingredients / Identity Information

Hazardous Components

(Specific Chemical Identity, Common Name(s))

CAS No.

OSHA PEL

ACGIH-TLV

 

NIOSH

%(Opt.)

Homologues of methylene bisphenyl

9016-87-9

N/D

N/D

N/D

5-10

isocyanate

 

 

 

 

 

Methylene bispheny isocyanate

101-68-8

3mg/m3

0.2 mg/

N/D

1-5

 

 

 

m3 ceiling (STEL)

 

 

     

 

 

0.02 ppm ceiling

 

     

 

 

 

(STEL)

 

 

Polypropylene Polyol

25322-69-4

N/D

N/D

N/D

5-15

 

 

 

 

 

 

This product is not known to contain any compounds listed and in quantities requiring reporting under SARA Title III Section 313.

Any substance listed as hazardous by the State of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania or

Texas is described above if known present in regulated concentrations.

Section III - Physical Chemical Characteristics

Boiling Point

 

     

Specific Gravity (H2O = 1)

1.22

Vapor Pressure (mm/Hg)

 

0.0003

Melting Point

N/A

Vapor Density (Air=1)

 

     

Evaporation Rate (Butyl Acetate=1)

     

Solubility in Water

 

Insoluble

pH

     

Appearance and Odor—

Fiberglass cloth , coated with viscous resin with no odor.

% Volatiles by Volume

Negligible

Section IV – Fire and Explosion Hazard Data

USA Flame Projection Test (ASTM D-3065)

Flammable Limits

LEL

UEL

Pensky-Martens Closed Cup

370ºF

N/A

N/A

Extinguishing Media – Carbon dioxide, foam, dry chemical.  Water spray for large fire.

Special Fire Fighting Procedures – Full emergency equipment with self-contained breathing apparatus and full protective clothing should be worn by firefighters.  During a fire, MDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or combustion.  At temperatures greater than 400ºF, polymeric MDI can polymerize and decompose which can cause pressure build-up in closed containers.  Explosive rupture is possible.  Therefore, use cold water to cool fire-exposed containers.

Unusual Fire and Explosion Hazards – None

Section V – Reactivity Data

Stability

 

Unstable

Conditions to Avoid – Contamination with water.  Contact with moisture, other materials, which can react with isocyanates or temperatures above 400ºF, may cause polymerization.

Hazardous

Polymerization

May Occur

x

Stable

x

Will Not Occur

Page 2 of 4 for B4151 Pipe Bond Repair Kit Pressure Off

Incompatibility (Materials to Avoid) –

Water, amines, strong bases, alcohols.  Will cause some corrosion to copper alloys and aluminum.

Hazardous Decomposition Products – Carbon monoxide, oxides of nitrogen, traces of HCN, MDI vapors or aerosols.

Hazardous Decomposition or Byproducts (Under Fire Conditions) –

Combustion produces carbon monoxide, oxides of nitrogen, and traces of HCN, MDI vapors or aerosols.

Section VI – Health Hazard Data

Route(s) of Entry:

 

Eyes?

Yes

Inhalation?

Yes

Skin?

Yes

Ingestion?

Yes

Health Hazards (Acute and Chronic) –

Acute Eyes—Liquid, aerosol, or vapor are irritating and can cause tearing, reddening and swelling.  If left untreated, corneal damage can occur and injury is slow to heal.  Damage, however is usually reversible.

Acute Skin—Isocyanates react with skin protein and moisture and can cause irritation, which may include the following symptoms: reddening, swelling, rash, scaling or blistering.  Cured materials are difficult to remove.

Acute Inhalation— Although MDI is low volatility, an inhalation hazard can exist from MDI aerosols or vapors formed during heating, foaming or spraying.  Can irritate mucous membranes, cause runny nose, sore throat, coughing, and other symptoms.

Acute Ingestion—Irritation and corrosive action can occur in the mouth, stomach tissue and digestive tract.  Symptoms can include: sore throat, abdominal pain, nausea, vomiting and diarrhea.

Chronic Effects— prolonged skin contact can cause reddening, swelling, rash, scaling or blistering and in some cases, skin sensitization.  Individuals who have skin sensitization can develop these symptoms from contact with liquid or vapor.  Animal tests have indicated that respiratory sensitization can result from skin contact with MDI.  These data reinforce the need to prevent direct skin contact with MDI.

Carcinogenicity:

NTP?

IARC Monographs?

OSHA Regulated?

 

No

No

No

Medical Conditions Generally Aggravated –Asthma, other respiratory disorders (bronchitis, emphysema, bronchial hyper reactivity), skin allergies, eczema.

Emergency and First Aid Procedures: 

Eyes—Flush with copious amount of water.  Preferably lukewarm, for at least 15 minutes, holding eyelids open at all times.  Refer individuals to a physician or ophthalmologist for immediate follow up.

Skin—Remove contaminated clothing.  Wash affected skin thoroughly with soap and water.  Wash contaminated clothing thoroughly before reuse.  For severe exposures, get under safety shower after removing clothing, then get medical attention.  For lesser exposures, seek medical attention if irritation develops or persists after area is washed.

Inhalation—Move to an area free from risk of further exposure.  Administer oxygen or artificial respiration as needed.  Obtain medical attention.  Asthmatic-type symptoms may develop and may b immediate or delayed up to several hours.  Consult physician should this development occur.

Ingestion—Do not induce vomiting.  Give one to two cups of milk or water to drink.  Do not give anything by mouth to an unconscious person consult a physician.

Section VII – Precautions For Safe Handling and Use

Steps to be Taken in Case Material is Released or Spilled–

Normal housekeeping practices.  Pick up and contain any spilled material.

Recommended Disposal– Dispose of materials according to the applicable Federal, State, or local regulations.

Precautions to be Taken in Handling and Storing –

No special procedures are necessary when handling this product.  Store in a well-ventilated, cool, dry place.

Section VIII – Control Measures

Respiratory Protection (Specify Type) –

Not required under anticipated use conditions.

Protective Gloves –

Permeation resistant gloves.

Eye Protection –.

Wear appropriate safety glasses with side shields

Ventilation –

Adequate

Other protective Clothing or Equipment – None

Work/Hygienic Practices – Observe goo

d hygiene.  Wash hands thoroughly after eating, drinking, and using restrooms, etc.

 

 

Material Safety Data Sheet

May be used to Comply with OSHA’s

Hazard Communication Standard,

 29 CFR 1910.1200.  Standard must be

Consulted for specific requirements

HMIS

HEALTH                                                   1        REACTIVITY                               0

FLAMMABILITY                                     1      PERSONAL PROTECTION          B

Identity (As Used On Label and List)

B4151 Pipe Bond- Repair Kit Pressure Off   Steelman

Note:  Blank spaces are not permitted.  If any item is not applicable, or no information is available, the space must be marked to indicate that.

Section I

Manufactured for:

OMEGA INDUSTRIAL SUPPLY, INC

Emergency Telephone Number:

1-800-424-9300

Address (Number, Street, City, State, and Zip Code)

101 Grobric Ct #1

Telephone Number for Information:

1-800-571-7347

Fairfield, CA 94534

Date Prepared

06-07-2005

 

 

Signature of Prepare (Optional)

REGULATORY DEPT.

Section II - Hazardous Ingredients / Identity Information

Hazardous Components

(Specific Chemical Identity, Common Name(s))

CAS No.

OSHA PEL

ACGIH-TLV

Other Limits

Recommended.

%(Opt.)

Glycidyl Ethers of Bisphenol A resins

25068-38-6

N/E

N/E

 

10-30

Tri (dimethylaminoethyl) phenol

90-72-2

0.10mg/m3

N/E

     

0.5-1.5

 

 

 

 

 

 

     

     

     

     

     

     

     

     

     

     

     

     

All ingredients in this product are listed in the T.S.C.A Inventory

 

 

Any substance listed as hazardous by the State of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania or

Texas is described above if known present in regulated concentrations.

 

 

 

Section III - Physical Chemical Characteristics

Boiling Point

 

     

Specific Gravity (H2O = 1)

Concentrate

1.9

%Volatile

 

0%

VOC

 

<1.0%

Vapor Density (Air=1)

 

     

Evaporation Rate (Butyl Acetate = 1)

 

     

Solubility in Water

 

Insoluble

Note: The physical data represented above are typical values and should not be construed as a specification.  For additional physical data and details on use please obtain a data sheet on this product.

Appearance and Odor— Metallic/white with mercaptan/sulfur odor.

Section IV – Fire and Explosion Hazard Data

Flammability Class

Flash Range

LEL

UEL

IIIB

None

N/A

N/A

Extinguishing Media – Water spray, CO2, dry chemicals.

Fire Fighting Procedures – Fire fighters and others who may be exposed to the product of combustion should be equipped with NIOSH-approved positive pressure self-contained breathing apparatus (SCBA) and full protective clothing.

Unusual Fire and Explosion Hazards – CO, aldehydes, acids, oxides of sulfur & nitrogen may be formed

 

Page 4 of 4 for B4151 Pipe Bond- Repair Kit  Pressure Off   Steelman

Section V – Reactivity Data

Stability

 

Unstable

Conditions to Avoid –

None

Stable

X

Incompatibility (Materials to Avoid) – None

Hazardous Decomposition or Byproducts – CO, aldehydes, acids, oxides of sulfur & nitrogen.

Hazardous

Polymerization

May Occur

Conditions to Avoid –

None

Will Not Occur

X

Section VI – Health Hazard Data

Route(s) of Entry:

 

Eyes?

Yes

Inhalation?

No

Skin?

Yes

Ingestion?

Yes

Health Hazards (Acute and Chronic) –

See Below

Carcinogenicity:

NTP?

IARC Monographs?

OSHA Regulated?

 

N/A

N/A

N/A

Signs and symptoms of Exposure:

Eyes— Possible irritation and sensitizer.

Skin— Possible irritation and sensitizer.

Inhalation—None

Ingestion—Irritation of intestinal tract.

Medical Conditions Generally Aggravated –None Known

Emergency and First Aid Procedures. 

Eyes—Flush with water, consult a physician.

Skin—Wash with soap and water.

Inhalation—Remove to fresh air.

Ingestion—Seek medical advice.  Do not give anything to an unconscious person.

Section VII – Precautions For Safe Handling and Use

Steps to be Taken in Case Material is Released or Spilled.

Dispose of in a normal manner.

Waste Disposal Method – Dispose of residue in accordance with federal, state and local regulations.

Precautions to be Taken in Handling and Storing –

Storage Temperature <90ºF (32ºC) Storage Conditions: Store in a cool, dry, well-ventilated area.

Other Precautions –

Container can be hazardous when empty.  Follow label cautions even after the container is empty since empty containers could retain product residues.  Do not re-use empty containers for food, clothing, or products for human or animal consumption or where skin contact can occur.

Section VIII – Control Measures

Respiratory Protection (Specify Type) –

None required unless sanding or abrading.

Ventilation

Local Exhaust

Only if heated above 100ºF (38ºC)

Special

 

Mechanical (General)

None Required

Other

 

Protective Gloves –Appropriate impervious gloves.  Because a variety of protective gloves exist, consult glove manufacturer to determine the proper type for a specific operation.

Eye Protection –

Safety glasses.

Other protective Clothing or Equipment – None Required

Work/Hygienic Practices – Observe good hygiene.  Wash hands thoroughly after eating, drinking, and using restrooms, etc.